The orbital energy second derivatives with respect to the CC asymmetric stretching mode of benzene, allyl cation and allyl anion show unambigiously that the ~r orbitals are unstable with respect to a distorted geometry with alternating CC bonds. It is the cr frame which enforces the D6h form of benz
β¦ LIBER β¦
Resonance Effect in the Allyl Cation and Anion: A Revisit
β Scribed by Mo, Yirong
- Book ID
- 111893509
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 99 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0022-3263
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