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Resolvent technique and Padé approximants in configuration interaction calculations

✍ Scribed by I. Røeggen

Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
576 KB
Volume
9
Category
Article
ISSN
0020-7608

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✦ Synopsis

Abstract

A perturbation approach based on resolvent technique and Padé approximants is proposed. The eigenvalue of interest is part of a solution of two nonlinear algebraic equations. The nonlinear equations are arrived at by considering two different expression of the expectation value of the resolvent of an outer projection of the Hamiltonian. The first expression is based on the spectral resolution of the resolvent, and the second one is obtained by a power series expansion analogous to that applied in the derivation of the energy expression in the Brillouin–Wigner perturbation theory. The truncated power series is extrapolated by Padé approximants of type II. The method is tested on a CI calculation of the energy of the lowest ^1^Σ state of the B~2~ molecule.

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