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Resolution of [(η4-benzylideneacetone)Fe(CO)3]. Structure and configurational stability of [(pS)-(benzylideneacetone)Fe(CO)2L★] (L★  (+)-neomenthyldiphenylphosphine)

✍ Scribed by A. Marcuzzi; A. Linden; D. Rentsch; W. von Philipsborn


Book ID
107812254
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
602 KB
Volume
429
Category
Article
ISSN
0022-328X

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Structural Study of the Conformational I
✍ Gudrun Hopp Rentsch; Daniel Nanz; Isabel Solana; Raina Stefanova; Wolfgang von P 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 554 KB

For the first time, 2D(3'P, s7Fe){1H}-triple-resonance NMR spectroscopy was used at low temperatures (213 and 179 K) to study the conformers of (q4-benzylideneacetone)-and (q4-diene)Feo(CO),L complexes (L = phosphanes, phosphites). In some cases not only the 57Fe chemical shifts and the 1J(57Fe, 31P