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Residual dipolar splittings in, 13C MAS NMR arising from interactions with chlorine nuclei

✍ Scribed by Robin K. Harris; M. Maral Sünnetçioǧlu; Kenneth S. Cameron; Frank G. Riddell

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
306 KB
Volume
31
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Residual dipolar splittings in ^13^C cross‐polarization magic‐angle spinning spectra arising from coupling to chlorine nuclei are reported for the three chloroacetanilide isomers, using several spectrometers. At medium to high magnetic field doublets are seen for CCl carbon resonances. Perturbation theory explains the appearance of the spectra qualitatively but is inadequate quantitatively.

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