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RESEARCHES ON THIOCYANATES AND ISOTHIOCYANATES. XII. THE POLYKETIDE ISOTHIOCYANATE—ETHYL ISOTHIOCYANPROPIONATE.

✍ Scribed by Johnson, Treat B.; Ticknor, Arthur A.


Book ID
120013285
Publisher
American Chemical Society
Year
1918
Tongue
English
Weight
754 KB
Volume
40
Category
Article
ISSN
0002-7863

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The mechanism of isomerization of allyl thiocyanate to allyl isothiocyanate has been investigated both experimentally and theoretically. The kinetic study indicates that the reaction is unimolecular and is not ionic. The entropy of activation suggests strongly that the mechanism involves a cyclic tr