Recently Gaffney and Levine [ 1 1 have examined various correlations for the rate constants for the gas phase reactions of O(3P) atoms and OH radicals with organics, i.e., linear free energy correlations for O(3P) atom and OH radical addition and abstraction reactions, the correlation of addition re
Reply to “comments on ‘predicting gas phase organic molecule reaction rates using linear free energy correlations. I. O(3P) and OH addition and abstraction reactions’”
✍ Scribed by J. S. Gaffney; S. Z. Levine
- Book ID
- 102447513
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 173 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0538-8066
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✦ Synopsis
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## Abstract Linear free‐energy (LFE) correlations for gas phase O(^3^P) and OH addition and abstraction reactions with a number of organic compounds have been established using existing room‐temperature rate constants evaluated from the literature. Addition reaction rate constant correlations with
Recently, Atkinson et al. [l] reported measurements on the reaction of ozone with a series of carbonyls. In that study a correlation between ozone addition and hydroxyl-radical addition reactions was employed to predict OH addition coefficients for acrolein and crotonaldehyde of approximately 2 X an