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Reply to comment “possible structures for trimethylene radical cations in freon matrices”

✍ Scribed by Xue-Zhi Qin; Larry D. Snow; Ffrancon Williams


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
247 KB
Volume
117
Category
Article
ISSN
0009-2614

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✦ Synopsis


The possible existen= of an interaction between lhe ring-opened cyclopropane radical cations and the CFClICF2CI solvent has beRl probed by ESR studies. No definitive evidence for this interaction has been obtined


📜 SIMILAR VOLUMES


Possible structures for trimethylene rad
✍ Martyn C.R. Symons 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 217 KB

1~ has recently been shown tbal the parent. cycbc struclure for the qclopropane radical cation undergo ring opening in a CFCi,CF,Cl matrix However, the ESR results show tiat the derived species has a SOMO loc~bsed on only one of the terminal CH, groups. This apparently requires a Limiting orthogonal