Warren has racendy applied the angular overlap model in the calculalion 01 Jahn-Tellsr cnrrgjti. Inconsistencies in this approach can be removed by the use of the more general superposition model. Nevertheless. in cases where insufficirnl dam exist lo delerminc all the superposition model pammekrs,
✦ LIBER ✦
Reply to angular overlap and superposition models of the orbit—lattice interaction
✍ Scribed by Keith D. Warren
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 125 KB
- Volume
- 122
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Not unexpectedly, the six-paramerer superposilion model (Shf) is more successful in trea[ing lanlhanide EPR strain data than the essenrinlly nw-parameter angular overlap model (AOM).
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## Abstract A temperature‐jump relaxation study of the interaction of tilorone with different polynucleotides and DNA has been performed. A single relaxation time, attributed to the intercalation step, has been observed in the case of poly[d(A‐T)]·poly[d(A‐T)], poly[d(A‐C)]·poly[d(G‐T)], poly[d(G‐C