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Reply: Standards of Demonstration for the Heterogeneous Photoreactions of N2 with H2O

✍ Scribed by Prof. Julian A. Davies; Prof. Jimmie G. Edwards


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
217 KB
Volume
105
Category
Article
ISSN
0044-8249

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The synthesis of ammonia from nitrogen and water by irradiation in the presence of certain metal oxide powders as catalysts has been published a number of times since 1977 but was called into question last year by Edwards et al. (__Angew. Chem. Int. Ed. Engl.__ 1992, 31, 480). Criticism of those arg

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Edwards et al. in their communication in essence convey the impression that the photoreduction of dinitrogen on heterogeneous photocatalysts is thermodynamically close to impossible and that the ammonia yields observed by previous workers''. 31 may have been due to erroneous measurements of backgrou