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Replacement of C−O by P−O in Cyclic Acetals and Ketals

✍ Scribed by Feng Wang; Shuguang Ma; W. Andy Tao; R. Graham Cooks

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
108 KB
Volume
38
Category
Article
ISSN
0044-8249

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✦ Synopsis

Efficiency and structural specificity earmark the reaction of phosphonium ions 1 with cyclic acetals and ketals to yield 1,3,2-dioxaphospholanium ions 2 [Eq. (1)]. Potential applications of this reaction are in monitoring trace levels of organophosphorus esters and in developing novel carbonyl deprotection agents. R=OCH , CH ; R =H, CH ; R =CH , C H ; R =H, CH .

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