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Reorientational dynmics and internal rotation in W(PMe3)(CO)5

✍ Scribed by S.P. Wang; M. Schwartz

Book ID
103594255
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
672 KB
Volume
50
Category
Article
ISSN
0167-7322

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## Abstract Density functional calculations at the BP86/TZ2P level were carried out to understand the ligand properties of the 16‐valence‐electron(VE) Groupβ€…14 complexes [(PMe~3~)~2~Cl~2~M(E)] (1ME) and the 18‐VE Groupβ€…14 complexes [(PMe~3~)~2~(CO)~2~M(E)] (2ME; M=Fe, Ru, Os; E=C, Si, Ge, Sn) in co