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ReO2Cl(S2O7), ein molekulares Disulfat

✍ Scribed by Dipl.-Chem. Ulf Betke; Wilke Dononelli; Prof. Dr. Thorsten Klüner; Prof. Dr. Mathias S. Wickleder

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
401 KB
Volume
123
Category
Article
ISSN
0044-8249

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ReO2Cl(S2O7), a Molecular Disulfate
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The tendency of sulfuric acid to form polysulfates as condensation products is not as pronounced as for the less acidic neighbors in the periodic table, H 3 PO 4 and H 4 SiO 4 , for which numerous polyphosphates and polysilicates are known. Therefore, it is not surprising that the number of structur

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Kaliumheptachlorodioxodimolybdat(V), KMo
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✍ Susanne Rabe; Ulrich Müller 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 110 KB

KMo 2 O 2 Cl 7 was obtained at 400 °C from the reaction of SCl 2 with molybdenum which contained traces of potassium. Its crystal structure is monoclinic, space group C2/c, a = 1094.1, b = 1139.1, c = 1018.0 pm, b = 110.16°, Z = 4. In the Mo 2 O 2 Cl 7 ± ion two coordination octahedra share a common