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Renner-Teller Effect in HCCCl + (X̃ 2 Π) Studied by High Resolution Photoelectron Spectroscopy

✍ Scribed by Sun, Wei; Dai, Zuyang; Zhou, Yiyong; Mo, Yuxiang


Book ID
127030070
Publisher
Institute of Physics
Year
2014
Tongue
English
Weight
257 KB
Volume
488
Category
Article
ISSN
1742-6588

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The CaCCH 5 2 2 and 5 0 2 bands in the A ˜2P -X ˜2S / system, involving the excited Ca-C-C bending vibrations, have been rotationally analyzed via CW dye laser excitation and dispersed fluorescence with a CCD array detector. The A ˜2P £ 5 Å 2 level is subject to Renner -Teller and spin-orbit splitti