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REMPI and MATI spectroscopic study of selected cis and trans 3-chlorostyrene rotamers

โœ Scribed by Dong, Changwu; Zhang, Lijuan; Liu, Sheng; Hu, Lili; Cheng, Min; Du, Yikui; Zhu, Qihe; Zhang, Cunhao

Book ID
122058482
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
940 KB
Volume
292
Category
Article
ISSN
0022-2852

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Spectroscopic studies on olefinsโ€”III: NM
Spectroscopic studies on olefinsโ€”III: NMR of cis- and trans- disubstituted olefins
โœ F. H. A. Rummens; J. W. de Haan ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 362 KB

## Abstract The proton NMR spectra of four __cis__/__trans__ pairs of 1,2โ€disubstituted olefins have been analysed. The observed trends of the olefinic, vicinal and allylic protonโ€proton coupling constants are discussed in terms of rehybridization at the __sp__^2^ carbon atoms. It is found that in