Removal of water-soluble azo dye by the magnetic material MnFe2O4

✍ Scribed by Rongcheng Wu; Jiuhui Qu

• Publisher: Wiley (John Wiley & Sons)
• Year: 2004
• Tongue: English
• Weight: 161 KB
• Volume: 80
• Category: Article
• ISSN: 0268-2575
• DOI: 10.1002/jctb.1142

✦ Synopsis

Abstract

Magnetic ferrite material, MnFe~2~O~4~, as a novel adsorbent was prepared and characterized. Adsorption tests indicated that it is an excellent adsorbent for the removal of the azo dye Acid Red B (ARB) from water. After adsorbing ARB and recovery by the magnetic separation method, it can be regenerated by Fenton's reagent. The pseudo‐first‐order and second‐order kinetic models were used to describe the kinetic data and the rate constants were evaluated. The adsorption capacity was highly affected by the pH of the solution, and pH 3.8 was optimal. After regeneration, the adsorption capacity of MnFe~2~O~4~ increased significantly, which was the result of a decrease in average pore diameter, an increase in surface area of the adsorbent and the adsorption of ferric hydroxide produced in the regeneration reaction. The adsorption can be described with the Langmuir model and the maximum adsorption capacity for ARB was 53.8 mg g^−1^ adsorbent. FTIR study for ARB on MnFe~2~O~4~ indicated that the adsorption of ARB occurred via the azo group and the sulfonic group of the dye through the formation of a complex with the adsorbent surface. Copyright © 2004 Society of Chemical Industry