The biosorption of toxic metals from an aqueous mixture containing zinc, copper and nickel, in the presence of calcium and sodium ions (usual co-existing cations in related systems) has been investigated. Industrial biomass samples of different origin have been examined batchwise as effective sorben
Removal of toxic metal ions from aqueous systems by biosorptive flotation
✍ Scribed by Anastasios I Zouboulis; Nick K Lazaridis; Kostas A Matis
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2002
- Tongue
- English
- Weight
- 153 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0268-2575
- DOI
- 10.1002/jctb.663
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Biosorptive flotation was used as a combined operation for the simultaneous abstraction of nickel, copper and zinc ions from aqueous streams. Laboratory‐scale batch experiments, as well as pilot‐scale continuous experiments, have been conducted. Grape stalks, a by‐product of the winery industry, were used as sorbent material. The experimental procedure consisted of two consecutive stages: (i) biosorption, and (ii) flotation. The possibility of reusing biomass, after appropriate elution, was also examined. The main parameters examined were biomass concentration, particle size of sorbent, surfactant concentration, pH and flocculation. Flotation removals, following laboratory‐scale experiments, were found to be in the order of 100, 85 and 70% for copper, zinc and nickel, respectively. In pilot‐scale experiments, biomass sorption capacities were determined as 25 for copper, 81 for zinc and 7 µmol dm^−3^ for nickel. The order of biomass affinity regarding the studied metals was Cu > Zn > Ni. Short retention time and high effectiveness suggest that biosorptive flotation is a promising treatment process for the removal of toxic metals from contaminated aqueous solutions.
© 2002 Society of Chemical Industry
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