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Removal of OMe from tricarbonyl-1- or -2-methoxycyclohexa-1,-3-dieneiron complexes : a novel preparation of tricarbonyl-π-cyclohexadienyliron salts

✍ Scribed by A.J. Birch; M. Haas

Publisher: Elsevier Science
Year: 1968
Tongue: French
Weight: 110 KB
Volume: 9
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)75521-3

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✦ Synopsis

Tricarbonyl-l-and -2-methoxycyclohexa-1,3-dieneiron derivatives are readily available, although usually as mixtures, by reaction of iron carbonyls with the 1-methoxycyclohexa-1,4 dienes produced by reduction of methowbensenes with metal--nia solutions'. n-Dienyl salts, still containing Olde, can be obtained from these by hydride abstraction' in a manner analogous to the similar production of x-dienyl salts from alhylcyclohexa-1,3-

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✍ Whitton, Alan J. ;Kumberger, Otto ;Müller, Gerhard ;Schmidbaur, Hubert 📂 Article 📅 1990 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 878 KB