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Removal of Metal−Metal Bonding in a Dimetallic Paddlewheel Complex: Molecular and Electronic Structure of Bis(phenyl) Dirhodium(III) Carboxamidate Compounds

✍ Scribed by Wolf, Joffrey; Poli, Rinaldo; Xie, Jian-Hua; Nichols, Jason; Xi, Bin; Zavalij, Peter; Doyle, Michael P.


Book ID
126070461
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
462 KB
Volume
27
Category
Article
ISSN
0276-7333

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The X-ray crystal structures of 2,1l-bis(di-R-phosphinomethyl)benzo[c]phenanthrenes (R = Ph, t -Bu) are reported. Both ligands have the same conformation and the substitution of a Ph by a t -Bu group does not cause significant changes in the tetracyclic aromatic unit which shows the same distortions