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Remote Substituent Effects in Ruthenium-Catalyzed [2+2] Cycloadditions: An Experimental and Theoretical Study

โœ Scribed by Liu, Peng; Jordan, Robert W.; Kibbee, Steven P.; Goddard, John D.; Tam, William


Book ID
125995375
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
272 KB
Volume
71
Category
Article
ISSN
0022-3263

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โœ Shengrui Tong; Chunping Ma; Maofa Ge; Weigang Wang; Dianxun Wang ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 730 KB

The electronic structure and substituent effects (SEs) in 2-bromo-5-chlorothiophene, 2-bromo-5-methylthiophene, and 2-bromo-5-nitrothiophene have been investigated by HeI photoelectron spectroscopy (PES). The observed PES bands were analyzed by combining empirical arguments and theoretical methods.