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Remote secondary deuterium isotope effects

โœ Scribed by Jewett, John G.; Dunlap, R. P.

Book ID
127174847
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
265 KB
Volume
90
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

Energy-dependent reversal of secondary i
Energy-dependent reversal of secondary isotope effects on simple cleavage reactions: Tertiary amine radical cations with deuterium at remote positions
โœ Steen Ingemann; Steen Hammerum; Peter J. Derrick; Roel H. Fokkens; Nico M. M. Ni ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 377 KB

Deuterium substitution at remote sites gives rise to inverse secondary kinetic isotope effects on the a-cleavage of a number of tertiary amines in the ion source, but to normal isotope effects on reactions occurring in the field-free regions. The change from normal to inverse secondary isotope effec