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Remote Functionalization by Alkoxyl Radicals Generated by the Photolysis of Nitrite Esters: The Barton Reaction and Related Reactions of Nitrite Esters

โœ Scribed by Hiroshi Suginome

Publisher
John Wiley and Sons
Year
2004
Weight
52 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract The e.s.r. signal observed during the reaction of aniline and pentyl nitrite in benzene is shown to be due not to phenyldiazoxyl (Ph๏ฃฟN๏ฃพN๏ฃฟOยท), as previously reported, but to a mixture of pentyloxyphenylnitroxyl and diphenylnitroxyl radicals, this assignment being made with the aid of deu