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Remote functionalisation by ferrous ion-cupric ion induced decomposition of alkyl hydroperoxides

✍ Scribed by Ž. Čekovió; Lj. Dimttruević; G. Djokić; T. Srnić


Book ID
108372129
Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
641 KB
Volume
35
Category
Article
ISSN
0040-4020

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✍ Z̈ivorad Čeković; Milutin Cvetković 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 280 KB

In the ferrous ion induced decomposition of alkyl hydroperoxides in the presence of cupric halides or pseudohalides, intramolecular functionalization, with ligand transfer from cupric salts to S-carbon atom, is achieved. Alkoxy radicals containing more than four carbon atoms in an alkyl chain, gener