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Remote Control of the C-3–C-4 Double-Bond Epoxidation of a Chiral 1,2-Dihydroquinoline: Application to the Synthesis of (–)-(R)-Sumanirole (PNU-95666E)

✍ Scribed by Ludivine Jean-Gérard; Frédéric Macé; Anh Ngoc Ngo; Mickaël Pauvert; Hélène Dentel; Michel Evain; Sylvain Collet; André Guingant


Book ID
111977720
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
812 KB
Volume
2012
Category
Article
ISSN
1434-193X

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Reaction of A 2 CO 3 (A = K, Rb) with Sn and Se in an H 2 O/CH 3 OH mixture at 115±130 °C affords the isotypic selenidostannates(IV) A 6 Sn 4 Se 11 ´x H 2 O (A = K, x = 8) 1 and 2 whose discrete [Sn 4 Se 11 ] 6± anions each contain two corner-bridged ditetrahedral [Sn 2 Se 6 ] 4± species. Similar re