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Remote Asymmetric Induction in an Intramolecular Ionic Diels−Alder Reaction: Application to the Total Synthesis of (+)-Dihydrocompactin

✍ Scribed by Sammakia, Tarek; Johns, Deidre M.; Kim, Ganghyeok; Berliner, Martin A.


Book ID
121271411
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
84 KB
Volume
127
Category
Article
ISSN
0002-7863

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Intramolecular diels-alder reactions of
✍ Wayne M. Best; Dieter Wege 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 180 KB

Substituted benzynes can be trapped intramolecularty by an attached furan moiety and such a reaction has been used in the synthesis of the natura'LZy occurring o-naphthoquinone mansonone E. The intramolecular Diels-Alder reaction continues to enjoy considerable popularity, particularly in its appli