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Remote Activation of Nickel Catalysts for Ethylene Oligomerization

✍ Scribed by Yaofeng Chen; Gang Wu; Guillermo C. Bazan

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
137 KB
Volume
117
Category
Article
ISSN
0044-8249

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Oligomerization of ethylene to branched
Oligomerization of ethylene to branched alkenes using neutral phosphinosulfonamide nickel(II) complexes
✍ Michael J. Rachita; R. Leigh Huff; Jordan L. Bennett; Maurice Brookhart πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 202 KB πŸ‘ 1 views

A series of neutral phosphinosulfonamide complexes of nickel(II) were synthesized that catalyzed the oligomerization of ethylene to branched oligomers with average degrees of polymerization between 10 and 35. Branching numbers varied from 17 to 80 branches per 1000 carbons, depending on the catalyst