Remarks on the theory of diffusion in electrolyte solutions
β Scribed by Nobuo Yoshida
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 363 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
The assumptions usually made that the ionic atmosphere has spherical symmetry m the dlffuslon of binary electrolytes and that the electrophoretic effect IS negli@ble rn the tracer dllfusion of ions are pointed out Lo be incorrect when terms up 10 order M' in K (K is the Debye-Hiickel parameter) are constdered.
π SIMILAR VOLUMES
we compare the results of a new approximation for the interionic radial distribution function developed previously by Olivares and hlcQuarrie to those from the nonlinear Poisson-Boltzmamr equation for the highly-charged system of a spherical protein bearing a charge as high as 20 in an aqueous elect