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Remarks on the hydrochlorination of 1,4-polyisoprene

✍ Scribed by Golub, Morton A. ;Heller, Jorge

Publisher
Wiley (John Wiley & Sons)
Year
1964
Tongue
English
Weight
358 KB
Volume
2
Category
Article
ISSN
0449-2986

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A detailed account of the mechanism of crosslinking in the cis-1,4-polyisoprene (1R)tetramethylthiuram disulfide (TMTD ) -ZnO system is given. Many experimental observations were harmonized in terms of a radical mechanism, rather than an ionic mechanism. Electron spin resonance (ESR) spectra on the