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Remarkable Effect of a Silicon Group on the Stereoselectivity of Radical 5-exo- Trig Cyclizations

✍ Scribed by James, Philippe; Landais, Yannick

Book ID
126057384
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
88 KB
Volume
6
Category
Article
ISSN
1523-7060

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Effect of Temperature on 5-endo-and 4-exo-trig Radical Cyclizations of N-Vinylic Ξ±-Halo Amides. -The reaction course is found to depend on the temperature. The method provides a new entry to tetrahydroindoles as versatile synthetic intermediates.