𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Remarkable Diastereoselectivity in the Addition of Allylic and Unsaturated Diorganozinc Reagents to β-( N , N -Dialkylamino)-aldehydes

✍ Scribed by Soucy, Regina L.; Kozhinov, Denis; Behar, Victor


Book ID
127243796
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
77 KB
Volume
67
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Dibutylboron triflate promoted conjugate
✍ Pieter S. van Heerden; Barend C.B. Bezuidenhoudt; Daneel Ferreira 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 192 KB

The organocopper-Lewis acid system, RCu-TMEDA-BuzBOTf, is useful for conjugate addition to highly constrained chiral c~,lS-unsaturated N-acyl imidazolidiannes. In comparison with the corresponding TMSCi-activated reagents, Bu2BOTf exhibits a dramatic increase in reactivity during 1,4-addition of ben