✦ LIBER ✦

Relaxation of platinum-195 in tetracyanoplatinate(II) and hexacyanoplatinate(IV) in aqueous solutions

✍ Scribed by Roderick E. Wasylishen; James F. Britten

Publisher: John Wiley and Sons
Year: 1988
Tongue: English
Weight: 356 KB
Volume: 26
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260261208

No coin nor oath required. For personal study only.

✦ Synopsis

The mechanism of lp5Pt spin-lattice relaxation in aqueous solutions of Pt(CN)f-and Pt(CN)g-has been elucidated from variable-temperature T, measurements at 4.70 and 8.48 T. For Pt(CN)f-both the chemical shielding anisotropy and spin rotation mechanisms are important; for Pt(CN)f-the spin rotation mechanism completely dominates. The value of Au obtained for Pt(CN)f-is 2350 ppm, which is in excellent agreement with the value previously measured for the tetracyanoplatinate(I1) ion in a variety of salts in the solid state.

📜 SIMILAR VOLUMES

A pulse radiolysis study of some platinu

A pulse radiolysis study of some platinum(II) and platinum(IV) complex ions in aqueous solutions. The formation and characterization of platinum(I) and platinum(III) transients

✍ D.K. Storer; W.L. Waltz; J.C. Brodovitch; R.L. Eager 📂 Article 📅 1975 🏛 Elsevier Science ⚖ 770 KB

Nuclear magnetic resonance and relaxatio

Nuclear magnetic resonance and relaxation of 195Pt in platinum-palladium alloys

✍ A. Narath; H.T. Weaver 📂 Article 📅 1968 🏛 Elsevier Science 🌐 English ⚖ 252 KB

Proton magnetic relaxation in aqueous gl

Proton magnetic relaxation in aqueous glycerol solutions containing manganese(II) Ion

✍ Scott D. Kennedy; Robert G. Bryant 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 327 KB

The proton nuclear magnetic relaxation rate, 1/T1, is reported as a function of d5-glycerol concentration for aqueous manganese(II) ion solutions over a range of magnetic field strengths corresponding to proton Larmor frequencies between 0.01 and 38 MHz. The data are analyzed in terms of the Solomon

Mechanistic aspects of the oxidative fun

Mechanistic aspects of the oxidative functionalization of ethane and ethanol by platinum(II) salts in aqueous medium. Role of platinum(II) -olefin and platinum(IV) -alkyl intermediates

✍ Alan C. Hutson; Minren Lin; Naomi Basickes; Ayusman Sen 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 506 KB

Proton spin-lattice relaxation in aqueou

Proton spin-lattice relaxation in aqueous solution of the nickel(II) ion

✍ J Kowalewski; T Larsson; P.-O Westlund 📂 Article 📅 1987 🏛 Elsevier Science ⚖ 672 KB

Stabilization of praseodymium(IV) and te

Stabilization of praseodymium(IV) and terbium(IV) in aqueous carbonate solution

✍ D.E. Hobart; K. Samhoun; J.P. Young; V.E. Norvell; G. Mamantov; J.R. Peterson 📂 Article 📅 1980 🏛 Elsevier Science ⚖ 304 KB