## Abstract Rotational and vibrational relaxation of pure liquid dimethyldichlorosilane (DMDCS) at temperatures of 279, 293, 308 and 323 K and in carbon tetrachloride, dioxane, chloroform and cyclohexane solutions at 293 K were studied by Raman band shape analysis. The activation energy for molecul
Relaxation of molecular motions in dibromomethane by Raman band shape analysis
β Scribed by R. Prakash; G. Thyagarajan
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 234 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0377-0486
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π SIMILAR VOLUMES
New symmetrized angular auto-correlation functions (ACFs) are applied to the theoretical description of the lineshape of internal modes in the polarized light scattering and infrared absorption spectra of molecular crystals. The model of hindered molecular motion (HMM) used to simulate the ACFs invo
Relaxation calculations for rapidly spinning samples show that spin-lattice relaxation time (T 1Z ) anisotropy varies with the angle between the rotor spinning axis and the external field. When the rate of molecular motion is in the extreme narrowing limit, the measurement of T 1Z anisotropies for t