✦ LIBER ✦

Relativistic modifications of covalent bonding in heavy elements: Calculations for T1H

✍ Scribed by Kenneth S. Pitzer; Phillip A. Christiansen

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 316 KB
Volume: 77
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(81)85213-x

No coin nor oath required. For personal study only.

✦ Synopsis

To determine whether the "orthogonal trlplet bond" proposed by Pyper IS an Important factor In the bonding of hydrogen to a very heavy element wth a smgle p, ,z valence electron, we computed dlssocgtlon curves for TIH usmg fully relatlv-1st~ quantum methods Our results and hterature mformatlon mdlate that the orthogonal trlplet Interactron makes no slgmticant wntributlon to bondmg

📜 SIMILAR VOLUMES

Relativistic modifications of covalent b

Relativistic modifications of covalent bonding in heavy elements. the role of partial ionic character and π electrons on ligands

✍ N.C. Pyper 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 678 KB

The bondmg beween an element contammg a smgle valence electron occupymg a Duac-Fock F or p orbltal and (I) a group of different electronegatnWy harmg no r electrons, (II) a group contammg both IJ and n electrons havmg a large P+O elcltatlon energy, (IU) a halogen and (IV) another element hawng a sin

Finite element calculations for the defo

Finite element calculations for the deformation around model tunnels : Orr, T L L; Atkinson, J H; Wroth, C P In: Computer Methods of Tunnel Design, 1978, P121–144. Publ London, Instn of Civil Engineers, 1978, 196P

📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 97 KB 👁 2 views