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Relativistic effects in aromatic molecules

✍ Scribed by Ralph E. Christoffersen; G. G. Hall


Book ID
104792125
Publisher
Springer
Year
1966
Tongue
English
Weight
550 KB
Volume
4
Category
Article
ISSN
1432-2234

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A computationally effkknt method to account for two-electron relativistic effects in a spin-free no-pair Hamiltonian has been investigated. The approach amounts to a rno~~~t~on of integrak familiar from ~o~-re~at~v~st~~ theory and is therefore compatible with a variety of different correfation treat

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Recent interpretations of Evans' experiments on the oxygen-induced singlet-triplet transitions in aromatic molecules are briefly discussed. In addition to the oxygen-induced singlet-triplet absorption for naphthalene there is a second absorption band which is possibly due to a simultaneous transiti