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Relative Strengths of NH··O and CH··O Hydrogen Bonds between Polypeptide Chain Segments

✍ Scribed by Scheiner, Steve


Book ID
126916016
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
231 KB
Volume
109
Category
Article
ISSN
0022-3654

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✍ Steve Scheiner; Tapas Kar 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 875 KB

Previous calculations have revealed that the NHAEAEAEO bond between a dipeptide NH and a proton acceptor is considerably weaker when the dipeptide is in its extended C5 conformation than in the C7 structure. The present work uses quantum chemical methods to determine the underlying reason for this d