Underlying source of the relation betwee
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Steve Scheiner; Tapas Kar
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Article
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2007
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Elsevier Science
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English
⚖ 875 KB
Previous calculations have revealed that the NHAEAEAEO bond between a dipeptide NH and a proton acceptor is considerably weaker when the dipeptide is in its extended C5 conformation than in the C7 structure. The present work uses quantum chemical methods to determine the underlying reason for this d