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Relative stereochemistry of multistriatin (2,4-dimethyl-5-ethyl-6,8-dioxabicyclo[3.2.1]octane)

✍ Scribed by Gore, William E.; Pearce, Glenn T.; Silverstein, Robert M.

Book ID: 127116454
Publisher: American Chemical Society
Year: 1975
Tongue: English
Weight: 510 KB
Volume: 40
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00900a006

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## Abstract The absolute configuration of the new bicyclic acetal 2‐ethyl‐1,5‐dimethyl‐6,8‐dioxabicyclo[3.2.1]octane (1), identified as an aggregation pheromone of males of the beech bark beetle, __Taphrorychus bicolor__, was determined by unambiguous synthesis and NMR experiments. The syntheses of