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Relative stabilities of 1-(bicyclo(2.2.1)heptyllithium and 1-bicyclo(2.2.2)octyllithium

✍ Scribed by Peter T. Lansbury; Jack D. Sidler

Publisher: Elsevier Science
Year: 1965
Tongue: French
Weight: 196 KB
Volume: 6
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)90020-0

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✦ Synopsis

In earlier studies of the Wittig Rearrangement of benzyl t-alkyl ethers 132 , we observed that isomerization of 1-adamantyl, 1-bicyclooctyl and acyclic t-alkyl groups occurred readily, whereas 1-apocamphyl and 1-norbornyl benzyl ethers did not isomerize when metalated by methyllithium.

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