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Relative Reactivity of Aromatic Double Bonds

✍ Scribed by BADGER, G. M.; REED, R. I.

Book ID
109554094
Publisher
Nature Publishing Group
Year
1948
Tongue
English
Weight
104 KB
Volume
161
Category
Article
ISSN
0028-0836

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πŸ“œ SIMILAR VOLUMES

Aromatic Sulfonation, 130. – Relative In
Aromatic Sulfonation, 130. – Relative Intramolecular Reactivity of the Insulated Ο€ Double Bond and the 14Ο€ Annulene Perimeter toward Sulfur Trioxide in the Sulfonation of Isopyrenes
✍ Cerfontain, Hans ;Bakker, Bert H. ;Koeberg-Telder, Ankie ;Wilmes, Oswald πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 471 KB

## Abstract The sulfonation of isopyrene (1) and its 5‐methyl‐ and 5,10‐dimethyl derivative 2 and 3 with SO~3~ in both dichloromethane and nitromethane as solvent has been studied. Reaction of 1 and 2 leads to sulfodehydrogenation in which SO~3~ reacts as a monodentate electrophile, the initial pro