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Relative Rates of Branching in Emulsion and Miniemulsion Polymerization

✍ Scribed by F. Joseph Schork; Fujun Lu


Book ID
112147180
Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
113 KB
Volume
3
Category
Article
ISSN
1862-832X

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πŸ“œ SIMILAR VOLUMES


Emulsion and miniemulsion polymerization
✍ Alan J. Back; F. Joseph Schork πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 182 KB

## Abstract Isobornyl acrylate, a highly hydrophobic monomer, was batch‐polymerized in both emulsion and miniemulsion recipes. Surfactant levels above and below the critical micelle concentration were used, as were two different initiator types: ionic (potassium persulfate) and nonionic (__t__‐buty

Long chain branching in emulsion polymer
✍ Alessandro Ghielmi; Stefano Fiorentino; Giuseppe Storti; Marco Mazzotti; Massimo πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 437 KB πŸ‘ 2 views

A kinetic model for evaluating the degree of polymerization of a branched polymer produced in emulsion is developed. Only chain branching occurring through chain transfer to polymer has been considered. The model accounts for chain compartmentalization and, when coupled to a model able to describe t