Relative rate coefficients of OH radical reactions with CF3CFCClCF3 and CF3CHCHCH2OH. Ozone depletion potential estimate for CF3CFCClCF3
✍ Scribed by Aranguren Abrate, Juan Pablo; Pisso, Ignacio; Peirone, Silvina Anahí; Cometto, Pablo Marcelo; Lane, Silvia Irene
- Book ID
- 125447582
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 830 KB
- Volume
- 67
- Category
- Article
- ISSN
- 1352-2310
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## Abstract The relative rate technique has been used to determine the rate constants of the reactions of OH radicals with CF~3~CClCCl~2~ (__k__~1~), CF~3~CClCClCF~3~ (__k__~2~) and CF~3~CFCFCF~3~ (__k__~3~). Experiments were carried out at (298±2) K and atmospheric pressure using ultrapure nitr
The rate constants for the reactions of OH radicals with CH 3 OCF 2 CF 3 , CH 3 OCF 2 CF 2 CF 3 , and CH 3 OCF(CF 3 ) 2 have been measured over the temperature range 250-430 K. Kinetic measurements have been carried out using the flash photolysis, laser photolysis, and discharge flow methods combine