Relative configuration of the C-1 to C-5 fragment of fumonisin B1
β Scribed by John W. ApSimon; Barbara A. Blackwell; Oliver E. Edwards; Alain Fruchier
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- French
- Weight
- 193 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The relative configuration of a methylated undecanehexaol, a fragment of amycin B, with five chirality centers was determined by a complete 1 H and 13 C signal assignment and interpretation of its acetonide derivatives.
Model compounds (11 and 12) for the C1-C10 tetrahydropyran fragment of amphidinol 2 were prepared from (2S)-benzyloxypropanal in 9 steps. The synthetic route relied on diastereoselective diene-aldehyde cycloaddition, stereoselective C-allylation, and reagent based enantioselective aldehyde allylatio