Relationships between dissociation energies and electrostatic potentials of CNO2 bonds: applications to impact sensitivities

A relationship between impact sensitivit

A relationship between impact sensitivity and the electrostatic potentials at the midpoints of CNO2 bonds in nitroaromatics

✍ Jane S. Murray; Pat Lane; Peter Politzer; Paul R. Bolduc 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 369 KB

We have modified and extended an earlier relationship between nitroaromatic impact sensitivity and electrostatic potentials at the midpoints of C-NO2 bonds. Because of the anomalous effect of the hydroxyl group on nitroaromatic sensitivities, possibly due to the formation of unstable nitronic acid t