Relationship of normal modes and local modes to normal coordinate treatment of liquid water
โ Scribed by D. Gellai
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 359 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0167-7322
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๐ SIMILAR VOLUMES
The C-F stretching fundamental and overtone spectra are reported for CFICll for up to fiie vibrational quanta A three-parameter local mode model accounts for both the frequencies and the relative intensities and provides a detailed description of the intramolecular dynamics following the excitation
The =CHI and =CD2 stretching vibrational overtones of H&-CD2 have been studied up to V= 6 and V= 3, respectively. We report their interpretation in terms of a transition from normal to local modes, involving Fermi resonance with the C-C stretching and CHz scissoring vibrations. We discuss the altern