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Relationship between the emission spectra and resonance Raman excitation profiles of W(CO)4(.alpha.-diimine) complexes

✍ Scribed by Servaas, Peter C.; Van Dijk, Hans K.; Snoeck, Theo L.; Stufkens, Derk J.; Oskam, Ad


Book ID
121203887
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
599 KB
Volume
24
Category
Article
ISSN
0020-1669

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Preparation, spectroscopic properties an
✍ H. Daamen; D.J. Stufkens; A. Oskam πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 English βš– 565 KB

## The binuclear complexes [ {M(C0)5}21.c-pyrazine] (M = 0, W) were readily prepared by heating the mononuclear compounds in an inert atmosphere. The spectroscopic data demonstrate that the M(CO)5 moieties in these complexes have retained C,, symmetry. The two allowed metal to pyrazine CT transition