Evidence that the β-Peptide 14-Helix is
✍
Tami L. Raguse; Jonathan R. Lai; Samuel H. Gellman
📂
Article
📅
2002
🏛
John Wiley and Sons
🌐
German
⚖ 136 KB
## Abstract Oligomers of __β__‐substituted __β__‐amino acids (‘__β__^3^‐peptides') are known to adopt a helical secondary structure defined by 14‐membered ring hydrogen bonds ('__14__‐helix'). Here, we describe a deca‐__β__^3^‐peptide, **1**, that does not adopt the __14__‐helical conformation and