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Relationship between Architecture and Adhesive Properties of Macromolecular Materials, 1

✍ Scribed by Amélie Baron; Eric Cloutet; Henri Cramail; Eric Papon

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
107 KB
Volume
204
Category
Article
ISSN
1022-1352

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✦ Synopsis

Abstract

This study deals with the preparation of polyurethane‐graft‐poly(n‐butyl acrylate)s copolymers by polymerization of diphenyl‐methane‐4,4‐di‐isocyanate (MDI) with α,α′‐di‐hydroxyl‐poly(n‐butyl acrylate)s of different sizes as macromonomers. The polyaddition has been studied on the basis of kinetic measurements, and the comb‐like structure of the resulting polymer has been well‐established. Such grafted copolymers display specific adhesive properties in connection with their comb‐like architecture.

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