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Relation between the thermodynamic parameters at the critical point and determination of the effective volumes of molecules

โœ Scribed by A. A. Sobko

Book ID
110207021
Publisher
SP MAIK Nauka/Interperiodica
Year
2008
Tongue
English
Weight
149 KB
Volume
53
Category
Article
ISSN
1028-3358

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The Thermodynamic Relations between the Melting Point and the Size of Crystals
โœ Yongqiang Xue; Qingsheng Zhao; Chunhui Luan ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 41 KB

The thermodynamic relations between the melting point (MP) and the size of crystals are derived by the use of the Kelvin equation. The results show that the MP depression increases with a decrease in size of a crystal and that there exists the lowest MP when the partial derivative of the surface ten