Relation between Electrical Properties and Cation-Anion-Cation Overlap in Nd(Cr1-xMnx)O3

Relationship between Crystal Structure a

Relationship between Crystal Structure and Electrical Properties of Nd(Cr1−xFex)O3

✍ Hideki Taguchi 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 323 KB

Perovskite-type Nd(Cr 1؊x Fe x )O 3 was synthesized in the range 0.04x41.0, and has the orthorhombic GdFeO 3 -type structure with space group Pnma. The increase of the (Cr, Fe)-O distance and the effective magnetic moment ( eff ) indicates that the Fe 3> ion is in the high-spin state with the (d ) 3