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Reinvestigation of the reaction of ethyl 4,4,4-trifluoroacetoacetate with aldehydes and ammonia

โœ Scribed by Baldev Singh; George Y. Lesher


Book ID
112126113
Publisher
Journal of Heterocyclic Chemistry
Year
1980
Tongue
English
Weight
92 KB
Volume
17
Category
Article
ISSN
0022-152X

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ChemInform Abstract: Reaction of Ethyl 4
โœ J. O. SMITH; B. K. MANDAL; R. FILLER; J. W. BEERY ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 1 views

Reaction of Ethyl 4,4,4-Trifluoroacetoacetate Enolate with 3-Bromo-1,1, 1-trifluoroacetone: Synthesis of 2,4-Bis(trifluoromethyl)furan. -The title reaction follows competing courses such as C-acylation, O-alkylation and di-O-alkylation which result in the formation of two major products (III) and (I