Reinvestigation of the Nazarov cyclization of 1-(3-hydroxypropynyl)cyclododecan-1-ol to bicyclo[10.3.0]pentadec-1(12)-en-13-one
โ Scribed by L. I. Zakharkin; V. V. Guseva; P. V. Petrovskii
- Book ID
- 105596190
- Publisher
- Springer
- Year
- 1997
- Tongue
- English
- Weight
- 233 KB
- Volume
- 46
- Category
- Article
- ISSN
- 1573-9171
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
**A Synthesis of Bicyclo[10.3.0]pentadecโ1(12)โenโ13โone and its 14โMethyl Derivative.** A new route to bicyclo[10.3.0]pentadecโ1(12)โenโ13โone (**2**) and its 14โmethyl derivative **3** โ useful intermediates in the synthesis of cyclopentadecanone (**4** = exaltoneยฎ) and __rac__โmuscone (**5**) โ
The anionic [1,3] rearrangement of both stereoisomenc bicyclo[3.2.1]oct-6-en-2-ols by treatment with KN(TMS)2 in toluene or in diglyme took place as a stereoconvergent route giving each of the stereoisomeric hydroxydiquinanes.