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Reinvestigation of the Isotope Effects for the Claisen and Aromatic Claisen Rearrangements: The Nature of the Claisen Transition States

โœ Scribed by Meyer, Matthew P.; DelMonte, Albert J.; Singleton, Daniel A.


Book ID
121228375
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
146 KB
Volume
121
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


The transition state of the claisen and
โœ Kenichi Fukui; Hiroshi Fujimoto ๐Ÿ“‚ Article ๐Ÿ“… 1966 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 149 KB

THE double allylic (the Claisen and the Cope) rearrangementa are known to take place through an intramolecular, cyclic transtion state. The preferable form of the transition state has been demonstrated to be chairlike rather than boatlike. 1.2 Recently Hoffmann and Woodward discussed this problem fr